Product ID:3910 SODIUM SULFIDE, 9-HYDRATE
MSDS Date:05/08/1995
FSC:6810
NIIN:00-234-8378
MSDS Number: CBRXF

Emergency Phone: 908-859-2151/800-424-9300(CHEMTREC)

Info Phone: 800-JTBAKER

Cage: 70829

Telephone: 800-582-2537

Cage: 70829

SODIUM SULFIDE NONAHYDRATE/SODIUM SULPHIDE

CAS: 1313-84-4

RTECS: WE1925000

Fraction By Weight: 98-100%

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:IRRIT OF UPPER RESP TRACT.
SKIN/EYE:SEVERE BURNS. SKIN ABSORPTION:MAY BE HARMFUL.
INGEST:SEVERE BURNS TO
MOUTH/THROAT/STOMACH,NAUSEA,VOMITING,DIARRHEA. CHRONIC EFFECTS:NONE
IDENTIFIED.
Explanation of Carcinogenicity:PER
MSDS:CARCINOGENICITY:NTP/IARC/ZLIST/OSHA:NO.
Effects of Overexposure:IRRIT OF UPPER RESP TRACT. SEVERE EYE/SKIN
BURNS. SKIN ABSORBTION HARMFUL. SEVERE BURNS TO
MOUTH/THROAT/STOMACH, NAUSEA, DIARRHEA, VOMITING.
Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE, CENTRAL
NERVOUS SYSTEM DISORDERS. TARGET ORGANS:EYE/SKIN.

First Aid:INGEST:CALL PHYSICIAN.DO NOT INDUCE VOMIT.GIVE WATER,MILK,OR
MILK FO MAGNESIA IF CONSC. INHAL:REMOVE TO FRESH AIR.NOT BREATH
GIVE ART RESP;BREATH DIFFI GIVE OXY.PROMPT ACTION ESSENTIAL.
SKIN:IMMED FLU SH W/PLENTY OF WATER FOR @LEAST 15MINS.

Flash Point Method:CC
Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:USE WATER SPRAY.
Fire Fighting Procedures:WEAR PROPER PROT EQPMT & SCBA W/FULL FCPIECE
OPERATED IN POSTIVE PRESSRUE MODE.MOVE CNTNR FRM FIRE AREA W/O
RISK.USE WATER TO KEEP FIRE-EXPO CNTNR COOL.
Unusual Fire/Explosion Hazard:GIVES OFF FLAMM VAP.VAP MAY FORM EXPLO
MIXTURE W/AIR.CLSD CNTNR EXPO TO HEAT MAY EXPLODE.

Spill Release Procedures:WEAR SCBA/FULL PROT CLOTH.SHUT OFF IGN
SOURCES;NO FLARES/SMOKING/FLAMES IN AREA.CAREFULLY PLACE MATL INTO
CLEAN DRY CNTNR/COVER.REMOVE FROM AREA.FLUSH SPILL AREA W/WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PRODUCT MUST BE REFRIG
@3-8C(36-46F).KEEP CNTNR TIGHTLY CLSD.STORE IN COOL DRY WELL-VENTI
AREA AWAY FROM HEAT/SPARKS/FLAME.ISOLATE FRM INCOMP MATLS.
Other Precautions:SAF-T-DATA STORAGE COLOR CODE:RED STRIPE(STORE
SEPARATELY).

Respiratory Protection:NONE REQUIRED WHEN ADEQUATE VENTILATION
CONDITIONS EXIST.IF AIRBORNE CONC IS HIGH DUST/MIST RESP IS
RECOMMENDED.IF CONC EXCEEDS CAPACITY OF RESP SELF-CONTAINED
BREATHING APPARATUS IS ADVISED.
Ventilation:USE ADEQUATE GENERAL/LOC EXHAUST VENTIALTION TO KEEP
FUME/DUST LEVELS AS LOW AS POSSIBLE.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:SAFETY GOGGLES.
Other Protective Equipment:UNIFORM, APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH=13.5 (10% SOLN).

HCC:B1
Boiling Pt:B.P. Text:345F,174C
Melt/Freeze Pt:M.P/F.P Text:122F,50C
Decomp Temp:Decomp Text:NP
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:1.86
pH:SUPPLM
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:APPRECIABLE (>10%)
Appearance and Odor:SOLID, WHITE TO YELLOW CRYSTALS, SULFUR DIOXIDE
ODOR.
Percent Volatiles by Volume:0
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, MOST COMMON METALS.
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:HYDROGEN SULFIDE.

Waste Disposal Methods:DISPO IAW ALL APPLICABLE LOCAL, STATE AND
FEDERAL ENVIRONMENTAL REGULATIONS.SARA 313 TOXI CHEM/CERCLA HAZ
SUBST:NO.EAP HAZ WASTE NO:D002(CORR WASTE).

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This information is formulated for use by elements of the Department
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expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.